Showing posts with label ozone. Show all posts
Showing posts with label ozone. Show all posts

Care for the Ozone Layer


The stratosphere normally is cold and very dry. Global warming can increase water vapor in the stratosphere in a number of ways. Global warming causes the troposphere to warm and since warmer air holds more water vapor, the amount of water vapor in the troposphere is increasing. This can cause more water vapor to end up in the stratosphere as well, as described below.

Stratospheric Water Vapor over the Arctic

Around the time of the December Solstice, very little sunlight is reaching the Arctic and temperatures over land at higher latitudes can get very low. At the same time, global warming has made oceans warmer and this keeps air temperatures over water relatively warm in Winter. This can lead to a number of phenomena including sudden stratospheric warming and moistening of the stratosphere.

Sudden stratospheric warming is illustrated by the image on the right, showing temperatures in the stratosphere over Siberia as high as 12.7°C or 54.9°F on December 24, 2018, and temperatures as low as -84.8°C or -120.6°F over Greenland.

At the same time, relative humidity was as high as 100% in the stratosphere over the North Sea, as the second image on the right shows.

Moistening of the stratosphere was even more pronounced on December 24, 2016, as illustrated by the third image on the right.

Storms over the U.S.

Jennifer Francis has long pointed out that, as temperatures at the North Pole are rising faster than at the Equator, the Jet Stream is becoming wavier and can get stuck in a 'blocking pattern' for days, increasing the duration and intensity of extreme weather events.

This can result in stronger storms moving more water vapor inland over the U.S., and such storms can cause large amounts of water vapor to rise high up in the sky.

Water vapor reaching stratospheric altitudes causes loss of ozone, as James Anderson describes in a 2017 paper and discusses in the short 2016 video below.


Methane

Stratospheric water vapor can also result from methane oxidation in the stratosphere. Methane concentrations have risen strongly at higher altitudes over the years. Noctilucent clouds indicate that methane has led to water vapor in the upper atmosphere.

The danger is that, as the Arctic Ocean keeps warming, large eruptions of methane will occur from the seafloor. Ominously, high methane levels have recently shown up on satellite images over the Arctic at lower altitudes, indicating the methane is escaping from the sea.

The images below show methane levels recorded by the NPP satellite:
Jan. 6, 2019, with peak levels of 2513 ppb at 1000 mb, 2600 ppb at 840 mb and 2618 ppb at 695 mb;
Jan. 11, 2019, with peak levels of 2577 ppb at 1000 mb, 2744 ppb at 840 mb and 2912 ppb at 695 mb;
Jan. 15, 2019, with peak levels of 2524 ppb at 1000 mb, 2697 ppb at 840 mb and 2847 ppb at 695 mb.

















The images below show methane levels recorded by the MetOp satellites:
Jan. 15, 2019, with peak levels of 2177 ppb at 840 mb, 2342 ppb at 695 mb and 2541 ppb at 586 mb;
Jan. 16, 2019, with peak levels of 2219 ppb at 840 mb, 2299 ppb at 695 mb and 2475 ppb at 586 mb;
Jan. 19, 2019, with peak levels of 2201 ppb at 840 mb, 2489 ppb at 695 mb and 2813 ppb at 586 mb.
















The Importance of the Ozone Layer

Increases in stratospheric water vapor are bad news, as they speed up global warming and lead to loss of stratospheric ozone, as Drew Shindell pointed out back in 2001.

It has long been known that deterioration of the ozone shield increases ultraviolet-B irradiation, in turn causing skin cancer. Recent research suggest that, millions of years ago, it could also have led to loss of fertility and consequent extinction in plants and animals (see box right).

Existential Threats

In conclusion, rising levels of emissions by people constitute existential threats in many ways. Rising temperatures cause heat stress and infertility, and there are domino effects. Furthermore, stratospheric ozone loss causes cancer and infertility. Only once the ozone layer formed on Earth some 600 million years ago could multicellular life develop and survive. Further loss of stratospheric ozone could be the fastest path to extinction for humanity, making care for the ozone layer imperative.

As described in an earlier post, Earth is on the edge of runaway warming and a moist-greenhouse scenario means oceans are evaporating into the stratosphere with loss of the ozone layer.

The situation is dire and calls for comprehensive and effective action, as described in the Climate Plan.


Links

• Climate and ozone response to increased stratospheric water vapor, by Drew Shindell (2001)
https://agupubs.onlinelibrary.wiley.com/doi/abs/10.1029/1999GL011197

• Stratospheric ozone over the United States in summer linked to observations of convection and temperature via chlorine and bromine catalysis, by James Anderson et al. (2017)
https://www.pnas.org/content/114/25/E4905

• Harvard Speaks on Climate Change: James Anderson (2016)
https://vimeo.com/185794598

• Climate Week: Climate Science Breakfast with James Anderson (April 9, 2015)
http://environment.harvard.edu/climate-week-climate-science-breakfast-james-anderson

• 10°C or 18°F warmer by 2021?
https://arctic-news.blogspot.com/2017/04/10c-or-18f-warmer-by-2021.html

• Noctilucent clouds indicate more methane in upper atmosphere
https://arctic-news.blogspot.com/2012/09/noctilucent-clouds-indicate-more-methane-in-upper-atmosphere.html

• Noctilucent clouds: further confirmation of large methane releases
https://methane-hydrates.blogspot.com/2013/12/noctilucent-clouds-further-confirmation-of-large-methane-releases.html

• It could be unbearably hot in many places within a few years time
https://arctic-news.blogspot.com/2016/07/it-could-be-unbearably-hot-in-many-places-within-a-few-years-time.html

• Climate change: effect on sperm could hold key to species extinction, by Kris Sales
https://theconversation.com/climate-change-effect-on-sperm-could-hold-key-to-species-extinction-107375

• Climate change: effect on sperm could hold key to species extinction
https://theconversation.com/climate-change-effect-on-sperm-could-hold-key-to-species-extinction-107375

• UV-B–induced forest sterility: Implications of ozone shield failure in Earth’s largest extinction, by Jeffrey Benca et al. (2018)
http://advances.sciencemag.org/content/4/2/e1700618

• Co-extinctions annihilate planetary life during extreme environmental change, by Giovanni Strona and Corey Bradshaw (2018)
https://www.nature.com/articles/s41598-018-35068-1

• Earth is on the edge of runaway warming
https://arctic-news.blogspot.com/2013/04/earth-is-on-the-edge-of-runaway-warming.html

• Climate Plan
https://arctic-news.blogspot.com/p/climateplan.html



Can we weather the Danger Zone?

[ click on image to enlarge ]
As an earlier Arctic-news analysis shows, Earth may have long crossed the 1.5°C guardrail set at the Paris Agreement.

Earth may have already been in the Danger Zone since early 2014. This is shown by the image on the right associated with the analysis, which is based on NASA data that are adjusted to reflect a preindustrial baseline, air temperatures and Arctic temperatures.

As the added 3rd-order polynomial trend shows, the world may also be crossing the higher 2°C guardrail later this year, while temperatures threaten to keep rising dramatically beyond that point.

What is the threat?

As described at the Threat, much carbon is stored in large and vulnerable pools that have until now been kept stable by low temperatures. The threat is that rapid temperature rise will hit vulnerable carbon pools hard, making them release huge amounts of greenhouse gases, further contributing to the acceleration of the temperature rise.


Further release of greenhouse gases will obviously further speed up warming. In addition, there are further warming elements that could result in very rapid acceleration of the temperature rise, as discussed at the Extinction page.

The Danger Zone

Below are some images illustrating just how dire the situation is, illustrating how vulnerable carbon pools are getting hit exactly as feared they would be with a further rise in temperature.

On July 5, 2018, it was as hot as 33.5°C or 92.3°F on the coast of the Arctic Ocean in Siberia (at top green circle, at 72.50°N). Further inland, it was as hot as 34.2°C or 93.5°F (at bottom green circle, at 68.6°N).


The satellite image below shows smoke from fires over parts of Siberia hit strongly by heat waves.


The fires caused carbon monoxide levels as high as 20,309 ppb over Siberia on July 3, 2018.


Methane levels that day were as high as 2,809 ppb.


On July 4, 2018, forest fires near the Lena River cause smoke over the Laptev Sea and East Siberian Sea. CO (see inset) and CO₂ levels that day were as high as 45080 ppb and 724 ppm (at the green circle), as illustrated by the image below.


The Copernicus image below shows aerosol forecasts for July 4, 2018, 21:00 UTC, due to biomass burning.


Another Copernicus forecast shows high ozone levels over Siberia and the East Siberian Sea.


EPA 8-hour ozone standard is 70 ppb and here's a report on recent U.S. ozone levels. See Wikipedia for more on the strong local and immediate warming impact of ozone and how it also makes vegetation more vulnerable to fires.

The global 10-day forecast (GFS) below, run on July 3, 2018, with maximum 2 meter temperature, shows that things may get even worse over the coming week or more.


Could we move out of the Danger Zone?

What can be done to improve this dire situation?

One obvious line of action is to make more effort to reduce emissions that are causing warming. There's no doubt that this can be achieved and has numerous benefits, as described in an earlier post. Emission cuts can be achieved by implementing effective policies to facilitate changes in energy use, in diet and in land use and construction practices, etc.

One complication is that the necessary transition away from fossil fuel is unlikely to result in immediate falls in temperatures. This is the case because there will be less sulfur in the atmosphere to reflect sunlight back into space. Furthermore, there could also be an increase in biomass burning, as discussed at the Aerosols page, while the full wrath of recent carbon dioxide emissions is yet to come. As said, the resulting rise in temperature threatens to trigger numerous feedbacks that could accelerate the temperature rise even further. For more on how much temperatures could rise, see the Extinction page.

While it's clear that - besides emission cuts - further action is necessary, such as removing greenhouse gases from the atmosphere and oceans, the prospect is that such removal will have to continue for decades and decades to come before it can bring greenhouse gases down to safer levels. To further combat warming, there are additional lines of action to be looked at, but as long as politicians remain reluctant to even consider pursuing efforts to reduce emissions, we can expect that the world will be in the Danger Zone for a long time to come.

The situation is dire and calls for comprehensive and effective action, as described in the Climate Plan.



Links

• How much warmer is it now?
https://arctic-news.blogspot.com/2018/04/how-much-warmer-is-it-now.html

• 100% clean, renewable energy is cheaper
https://arctic-news.blogspot.com/2018/02/100-clean-renewable-energy-is-cheaper.html

• Feedbacks
https://arctic-news.blogspot.com/p/feedbacks.html

• How much warming have humans caused?
https://arctic-news.blogspot.com/2016/05/how-much-warming-have-humans-caused.html

• IPCC seeks to downplay global warming
https://arctic-news.blogspot.com/2018/02/ipcc-seeks-to-downplay-global-warming.html

• The Threat
https://arctic-news.blogspot.com/p/threat.html

• Extinction
https://arctic-news.blogspot.com/p/extinction.html

• Aerosols
https://arctic-news.blogspot.com/p/aerosols.html

• How extreme will it get?
https://arctic-news.blogspot.com/2012/07/how-extreme-will-it-get.html

• Climate Plan
https://arctic-news.blogspot.com/p/climateplan.html


A Global Temperature Rise Of More than Ten Degrees Celsius By 2026?

How much have temperatures risen and how much additional warming could eventuate over the next decade? The image on the right shows a potential global temperature rise by 2026 from pre-industrial levels. This rise contains a number of elements, as discussed below from the top down.

February 2016 rise from 1900 (1.62°C)

The magenta element at the top reflects the temperature rise since 1900. In February 2016, it was 1.62°C warmer compared to the year 1900, so that's a rise that has already manifested itself.

Rise from pre-industrial levels to 1900 (0.3°C)

Additional warming was caused by humans before 1900. Accordingly, the next (light blue) element from the top down uses 0.3°C warming to reflect anthropogenic warming from pre-industrial levels to the year 1900.

When also taking this warming into account, then it was 1.92°C (3.46°F) warmer in February 2016 than in pre-industrial times, as is also illustrated on the image below.


Warming from the other elements (described below) comes on top of the warming that was already achieved in February 2016.

Rise due to carbon dioxide from 2016 to 2026 (0.5°C)

The purple element reflects warming due to the amount of carbon dioxide in the atmosphere by 2026. While the IEA reported that energy-related carbon dioxide emissions had not risen over the past few years, carbon dioxide levels in the atmosphere have continued to rise, due to feedbacks that are kicking in, such as wildfires and reduced carbon sinks. Furthermore, maximum warming occurs about one decade after a carbon dioxide emission, so the full warming wrath of the carbon dioxide emissions over the past ten years is still to come. In conclusion, an extra 0.5°C warming by 2026 seems possible as long as carbon dioxide levels in the atmosphere and oceans remain high and as temperatures keep rising.

Removal of aerosols masking effect (2.5°C)

With dramatic cuts in emissions, there will also be a dramatic fall in aerosols that currently mask the full warming of greenhouse gases. From 1850 to 2010, anthropogenic aerosols brought about a decrease of ∼2.53 K, says a recent paper. While on the one hand not all of the aerosols masking effect may be removed over the next ten years, there now are a lot more aerosols than in 2010. A 2.5°C warming due to removal of part of the aerosols masking effect therefore seems well possible by the year 2026.

Albedo changes in the Arctic (1.6°C) 

Warming due to Arctic snow and ice loss may well exceed 2 W per square meter, i.e. it could more than double the net warming now caused by all emissions by people of the world, calculated Professor Peter Wadhams in 2012. A 1.6°C warming due to albedo changes (i.e. decline of both Arctic sea ice and snow and ice cover on land) therefore seems well possible by the year 2026.

Methane eruptions from the seafloor (1.1°C)

". . we consider release of up to 50 Gt of predicted amount of hydrate storage as highly possible for abrupt release at any time," Dr. Natalia Shakhova et al. wrote in a paper presented at EGU General Assembly 2008. Authors found that such a release would cause 1.3°C warming by 2100. Note that such warming from an extra 50 Gt of methane seems conservative when considering that there now is only some 5 Gt of methane in the atmosphere, and over a period of ten years this 5 Gt is already responsible for more warming than all the carbon dioxide emitted by people since the start of the industrial revolution. Professor Peter Wadhams co-authored a study that calculated that methane release from the seafloor of the Arctic Ocean could yield 0.6°C warming of the planet in 5 years (see video at earlier post). In conclusion, as temperatures keep rising, a 1.1°C warming due to methane releases from clathrates at the seafloor of the world's oceans seems well possible by the year 2026.

Extra water vapor feedback (2.1°C)

Rising temperatures will result in more water vapor in the atmosphere (7% more water vapor for every 1°C warming), further amplifying warming, since water vapor is a potent greenhouse gas. Extra water vapor will result from warming due to the above-mentioned albedo changes in the Arctic and methane releases from the seafloor that could strike within years and could result in huge warming in addition to the warming that is already there now. As the IPCC says: "Water vapour feedback acting alone approximately doubles the warming from what it would be for fixed water vapour. Furthermore, water vapour feedback acts to amplify other feedbacks in models, such as cloud feedback and ice albedo feedback. If cloud feedback is strongly positive, the water vapour feedback can lead to 3.5 times as much warming as would be the case if water vapour concentration were held fixed", according to the IPCC. Given a possible additional warming of 2.7°C due to just two elements, i.e. Arctic albedo changes and seafloor methane, an additional warming over the next decade of 2.1°C due to extra water vapor in the atmosphere therefore does seem well possible by the year 2026.

Further feedbacks (0.3°C)

Further feedbacks will result from interactions between the above elements. Additional water vapor in the atmosphere and extra energy trapped in the atmosphere will result in more intense storms and precipitation, flooding and lightning. Flooding can cause rapid decomposition of vegetation, resulting in strong methane releases. Furthermore, plumes above the anvils of severe storms can bring water vapor up into the stratosphere, contributing to the formation of cirrus clouds that trap a lot of heat that would otherwise be radiated away, from Earth into space. The number of lightning strikes can be expected to increase by about 12% for every 1°C of rise in global average air temperature. At 3-8 miles height, during the summer months, lightning activity increases NOx by as much as 90% and ozone by more than 30%. The combination of higher temperatures and more lightning will also cause more wildfires, resulting in emissions such as of methane and carbon monoxide. Ozone acts as a direct greenhouse gas, while ozone and carbon monoxide can both act to extend the lifetime of methane. Such feedbacks may well result in an additional 0.3°C warming by the year 2026.

Total potential global temperature rise by 2026 (10°C or 18°F)

Adding up all the warming associated with the above elements results in a total potential global temperature rise (land and ocean) of more than than 10°C or 18°F within a decade, i.e. by 2026. As said before, this scenario assumes that no geoengineering will take place over the next decade.

The situation is dire and calls for comprehensive and effective action as described in the Climate Plan.



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